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ÇOK KATMANLI AMBALAJ FİLMLERİ
ve
TEKNİK ÖZELLİKLERİ
Muharrem DEMiR
www.apack.com.tr
2 KATMANLI
PA 30 microns
PA=Polyamide (substrate film)
PA/PE 30/70
PE 70 microns
5 KATMANLI
7 KATMANLI
PE=Polyethylene (sealing layer)
PA
HV
EVOH
HV
PE
=
=
=
=
=
Polyamide
Tie layer
Gas barrier
Tie layer
Polyethylene
PE
HV
PA
EVOH
HV
PA
HV
PE
=
=
=
=
=
=
=
=
Polyethylene
Tie layer
Polyamide
Gas barrier
Tie layer
Polyamide
Tie layer
Polyethylene
Yukarıda gösterilen 5 ve 7 katmanlı filmler stadart coextrude filmlerdir.
Bunlar Bloom veya Chill Roll yöntemleriyle üretilebilirler.
Çok Katmanlı Lamine Edilmiş Filmler
PETP
= Polyester
Adhesive
Aliminium foil
Adhesive
PE
= Polyethylene
Kalıpta çekilerek lamine edilen çok katmanlı kaplama filmler
Kağıt (with primer)
Bağlama Katmanı* = Ğolyethylene hamuru
Aluminyum folyo, 9 mikron
PE kaplama
Surlyn kaplama
Mono filmler gibi, çok katmanlı kombinasyonlar genellikle zemin veya kapak
üretiminde kullanılır. PVC, PETP, PS, OPS, PAN, PP ya da PC gibi sert filmler
ağırlıklı olarak monofilm üretiminde kullanılır. 100% e yakın esneklik derecesinde
olan filmler ise çok katlı kombinasyonlarda kullanılmaktadır.
Coextrusion
Blown film or cast film from a chill rol unit
Lamination
Adhesive or extrusion lamination
Coating
Extrusion coating or coextrusion coating
Coating (solution/dispersion)
HS lacquer, hotmelt, PVdC, Cold seal lacquer
Adhesive laminaation
LAMİNASYON
This line can also be used to produce combinations like PETP/Al/PE
Extrusion laminaation
LAMİNASYON
In this laminating process, PE in melt form is used as teh laminating agent.
KAPLAMA
In the coating process, the PE is cast from the slot die onto the substrate material
that is to be coated. The quality od teh combination is inferior to an adhesive
laminate in every respect. Production is, however, less expensive
COEXTRUSION YÖNTEMİYLE KAPLAMA
When low sealing temperatures are required – to use a cheap PE as a basis and a thin
Layer of expensive Surlyn as an agent that seals at low temperatures.
Coextrusion Chill Roll Süreci
PP/EVOH/PP, PS/PE, PS/EVOH/PE, PS/PETP
PA/PE, PE/PA/PE, PA/EVOH/PA/PE
20 to 2000 microns
Coextrusion line for multilayer films from e.g. 500 to 1200 mic. (for sterilisable
meal trays etc.) or flexible multilayer films made from PA, EVOH, PE, 100-300 micron
Blown Film Coextrusion
Only flexible multilayer films
PA/PE, PE/PA/PE, PA/EVOH/PA/PE
Combinations PA/EVOH/PA, PE/EVOH/PE
Printing of Film
Flexo Printing
Photocell point: register-printed
Gravure Printing
Flexo printing has always been less expensive, particularly with runs of less than
50.000 metres.
A further distinction is made between surface printing and reverse printing. Reverse
printing is more common.
Surface printing is only used for monofilms such as PVC and for multilayer films
that have been coextruded, PA/PE.
- Surface printing, where the ink is on the out side of the pack
- Reverse printing is normally applied to an inner layer, so that it is protected
against all external influences
- The colours are also given greater depth when the printing is covered by the
transparent outer layer of the film
- In reverse printing the colour that is on top in the print motif is printed first
and the white background is only added at the end.
Printing of Film
Flexo Printing
Printing of Film
Gravure Printing
MONOFİLMLERİN ÖZELLİKLERİ
MONOFİLMLERİN ÖZELLİKLERİ
Water vapour transmission
Gas barrier (O2, CO2 and N2)
Protection against aroma loss
Light barrier
Resistance of chamicals etc.
Temperature resistance
-
Feezing
Pasteurisation (95 ºC)
Boiling
Sterilisation (121 ºC)
NEM GEÇİRGENLİĞİ
Water vapour transmission is expressed in g/m2/24h with a difference
in relative humidity of 85% to 0%
Table comparing water vapour transmission;
according to DIN 53122 (individual films)
PA
OPA
Amorphous PETP
Oriented PETP
PS
PVC
PP
OPP
PE
Alu
Cellulose film
NC lacquer
Cellulose film
PVdC lacquer
With a thickness of
40 mic
100 mic
20
10
15 mic
12 mic
20 mic
12 mic
500 mic
20
5
2
0,4
30
5,5
1,5
12
2,5
0,5
2,5
0,5
0,1
2
1
5
1
0
35 gr
25
35 gr
2,5
GAZ BARİYERİ
(Co-extruded) Barrier Films
Gas permeability is expressed in cm3/m2/bar/24h
Table comparing Oxygen permeability;
according to DIN 53380 (individual films)
PA
OPA
Amorphous PETP
Oriented PETP
PS
PVC
PP
OPP
PE
Alu
Cellulose film
NC lacquer
Cellulose film
PVdC lacquer
With a thickness of
40 mic
100 mic
25
10
15 mic
12 mic
20 mic
12 mic
35 gr
35 gr
500 mic
30
45
20
3,5
3000
100
1500
1500
40
500
300
8
125
3000
1500
300
80
1500
0
125
10
Development Priorities
(Coated) Barrier Films
Another way of achieving a barrier effect is by coating films
with certain barrier materials.
The following techniques are used to achieve this:
• Metalization
• Coating / vaporizing with inorganic materials
(such as SiOX or Al2O3)
• Plasma polymerization
• Coating with PVDC
• Coating with organic-inorganic hybrid polymers
Furthermore, NORDENIA TECHNOLOGIES GmbH has developed a barrier
coating based on PVOH. It has an excellent aroma and oxygen
barrier (O2 permeability at 23 °C and 50 % relative humidity: 11.5 cm³/m²*24h*bar). PVOH contains (in contrast to PVDC) no
chlorine. The coating is highly transparent, is printable and can
be laminated, so that it may also be used in laminate composites.
This coating, which is expensive compared to other barrier
materials, was primarily developed for niche and special
applications, as it can be applied, for example, to the whole
surface or as a printed pattern that repeats itself.
Material Choice
Before choosing a
factors:
Product protection
package
for
a
product
one
must
consider
a
number
Oxidation
Moisture gain or loss
Aromatic gain or loss
fat penetration
Light
Product influence
Acidic or fat products
Aromatic oils
Detergents
Mechanical protection
Shock absorption
Freeze or heat resistance
Moisture resistance
Handling endurance
Information requirements
Print quality
Print scope
Company colours
Packaging machines
Fit chain material-machine-product
capacity
Manpower
Consumer demands
Easy opening, re-closing
Handling endurance
Shelf adaptation
Environment
Costs
Per unit
Totally, with transport, etc.
of
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